
Originally Posted by
StupendousMan
The region of interest is a complex place consisting of several interacting entities. There is a source of relativistic electrons and nuclei, and there is a large cloud of cool molecular gas. Some of the relativistic particles are impinging on the very large cloud. When a relativistic electron or nucleus strikes a CO molecule directly, then of course the CO dissociates. But the products of such a primary collision then go off and strike other atoms and molecules, which strike other atoms and molecules, and so on in a cascade. The final collisions involve such small energies that any CO molecules involved simply are excited to a higher energy level.
A remnant, the spectrum of which does not have a shape given by the Planck function. In other words, a (supernova) remnant which is not simply a cloud of gas emitting radiation according to the black-body formula.
There are many other processes which can give rise to radiation: bremmstrahlung, synchrotron, etc. If those other processes dominate over simple collisions between particles with a common kinetic energy, then the result is a non-thermal spectrum.