No, it is not ADM related (btw, I have ADM on my list to learn up to end of 2012 :-)
Here you may find some references to Geroch decomposition, that should make it familiar :-)
I recommend to learn it a bit - many ATM threads (including this thread, mine own last thread and many other historical) are speculations that may be explained much easier while discussed with Geroch framework.
"Global structure of spacetimes, in General Relativity, An Einstein Centenary Survey,", Geroch, R., Horowitz, G. T. Cambridge University Press, Cambridge, 1979 (big part of the publication is about that)
“A space‐time calculus based on pairs of null directions”, R. Geroch, A. Held, and R. Penrose, J. Math. Phys. 1973 (almost all is about that)
"Global Aspects in Gravitation and Cosmology", Joshi, P. S. Oxford University Press, 1993 (partly about that)
And some more popular or more available publications:
"General relativity", Schmidt B.G., Springer, 2000r, page 43 (but only short general explanation)
Wikipedia short definition
Casual hierarhy of spacetimes on arXiv