Because it would be, as I said, obvious. Anyone in a
spacesuit, stranded in space, would think of it almost
immediately. It is just common sense. They would know
that even if they have a supply of items to throw away,
which they are willing to throw away (stuff taken on EVA
tends to be expensive), they are very unlikely to be able
to throw it in the right direction to make them get where
they want to go, rather than just tumble. A small jet of
air coming out of the spacesuit would allow more time
to fine-tune the direction of the thrust, by changing the
configuration of the body in response to the observed
direction of motion. Of course this means you'll run out
of air a lot sooner, so if you're also already low on air,
common sense might say to try something else instead.